Synthesis, Spectroscopic Properties and Single Crystal X-ray Structure of Dithiocyanato-N-bis[8-(diphenylphosphino)-quinoline]ruthenium(II)
Vol. 17 No. 2 (2022), Articles
Vol. 17 No. 2 (2022)

Synthesis, Spectroscopic Properties and Single Crystal X-ray Structure of Dithiocyanato-N-bis[8-(diphenylphosphino)-quinoline]ruthenium(II)

Articles
  • Mohammad A. Al-Wahish
  • Firas F. Awwadi
  • Hamdallah A. Hodali*
Mohammad A. Al-Wahish
Firas F. Awwadi
Hamdallah A. Hodali*
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Keywords

Ruthenium(II) complexes, 8-(Diphenylphosphino)quinoline, Thiocyanate, Trans-influence, Hybrid ligand.

How to Cite

Mohammad A. Al-Wahish, M. A. A.-W., Firas F. Awwadi, F. F. A., & Hamdallah A. Hodali* , H. A. H. . (2022). Synthesis, Spectroscopic Properties and Single Crystal X-ray Structure of Dithiocyanato-N-bis[8-(diphenylphosphino)-quinoline]ruthenium(II). Jordan Journal of Chemistry (JJC), 17(2), 85-89. Retrieved from https://jjc.yu.edu.jo/index.php/jjc/article/view/572
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Abstract

The new ruthenium complex, [Ru(N-P)2(SCN)2], where N-P = 8-(diphenylphosphino)quinoline, was prepared and characterized by FT-IR, UV-Vis spectrometry and X-ray crystallography. The complex crystallized in the monoclinic system with the space group P1211. The cell parameters are a = 9.9635(7) Å, b = 18.8967(9) Å, c = 11.2651(6) Å, α = γ = 90°, β = 110.474(7) °. The complex has a distorted octahedral structure with cis configuration for the thiocyanate groups. The bond-length analysis indicates the following order of trans-influence:  P > N(SCN-) > N(quinolone).

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